Add Web Programming Course from Harvard. (#4608)

* Update free-courses-en.md

This is a course from Harvard University's CS50 about Web Programming with Python and JavaScript.
You can know it is free  by looking at the 'CS50 Certificate' section you can read that you only need to pay for the certificate but the course is Free.

* Update free-courses-en.md

Resubmitted the PR by changing the title as given by the resource.

* Update free-courses-en.md

Resubmit PR with the title as given by the resource: CS50’s Web Programming with Python and JavaScript.
Added in Alphabetical List.
Sorry,but it is my first PR so struggling a little bit.

free-courses-en.md

@@ -599,6 +599,7 @@
 ### Web Development
 
 * [ASP.NET Core Tutorial For Beginners](https://www.youtube.com/playlist?list=PL6n9fhu94yhVkdrusLaQsfERmL_Jh4XmU) - Venkat (Pragim Technologies)
+* [CS50’s Web Programming with Python and JavaScript](https://cs50.harvard.edu/web/2020/) - Brian Yu,David J. Milan (edX Harvard CS50)
 * [Discover Flask - Full Stack Web Development with Flask](https://github.com/realpython/discover-flask)
 * [Flask(A Python Microframework) Tutorial](http://blog.miguelgrinberg.com/post/the-flask-mega-tutorial-part-i-hello-world)
 * [Free Code Camp](https://www.freecodecamp.org)